Bromine has 35 electrons, arranged 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p5. Written on the previous noble gas that is [Ar] 3d10 4s2 4p5, and the shells hold 2, 8, 18, 7 electrons from the innermost outwards.
Hund's rule leaves 1 unpaired electron in the ground state, which is what makes the free atom paramagnetic.
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